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CHBE 565-International Paper Co Seminar-Prof. Betar Gallant, Massachusetts Institute of Technology, "Interplays of Composition and Function in the Interphases of Metal Anodes" (host: Schoetz)

Event Type
Seminar/Symposium
Sponsor
Chemical & Biomolecular Engineering and International Paper Company
Location
116 Roger Adams Lab
Date
Dec 10, 2024   2:00 pm  
Contact
Christy Bowser
E-Mail
cbowser@illinois.edu
Phone
217-244-9214
Views
41
Originating Calendar
Chemical & Biomolecular Engineering - Seminars and Events

Abstract: The lithium (Li) metal anode offers significantly higher capacity than graphite and is therefore central to strategies to develop advanced rechargeable battery chemistries that meet range and performance targets for electric vehicles. Although closer than ever, Li anodes still cannot meet the >99.9% Coulombic efficiency (CE) consistently needed for >1,000 cycle life. This shortfall arises from uncontrolled reactivity at the solid electrolyte interphase (SEI) and resulting SEI properties, leading to inhomogeneous plating and stripping, continuous electrolyte consumption and loss of active Li inventory. Despite progress in electrolyte development, the lack of precise understanding of the SEI still hinders attempts to rationally design an improved interface towards bridging remaining gaps in CE.

To inform such efforts, our work is advancing quantitative techniques to yield insights into SEI phases and the hidden interplays between their chemistry, properties and function. We developed approaches to isolate and synthesize exemplar ionic and organic phases relevant to the native SEI at nanoscale thickness on Li metal. These interfaces are then interrogated via targeted electrochemical and spectroscopy techniques to reveal their phase-specific transport properties and chemical dynamics in different electrolytes. By extending these tools to native interfaces in high- and low-CE electrolytes alike, we are identifying effective performance descriptors to guide development of advanced electrolytes and additives. Most recently, such techniques helped to reveal that the leading phase underlying high performance of Li metal anodes is, unexpectedly, lithium oxide, opening new design trajectories for future electrolytes and reducing the reliance on costly, unsustainable yet pervasive fluorinated electrolytes. 

Finally, I will share some perspectives on comparisons and unique challenges for beyond-Li chemistries including sodium and calcium metal batteries and their electrolytes, with distinct interphase properties and requirements.

Bio: Betar M. Gallant is an Associate Professor and the Class of ‘22 Career Development Professor in the Department of Mechanical Engineering at MIT, where she leads the Energy and Carbon Conversion Laboratory. She obtained her SB, SM, and PhD degrees from the same department. Following her PhD, Dr. Gallant was a Kavli Nanoscience Institute Postdoctoral Fellow at Caltech. Her research group at MIT focuses on advanced battery chemistries and materials for high-energy primary and rechargeable batteries, including fluorinated cathode conversion reactions and lithium, sodium, and calcium metal anodes and their interfaces. Her group is also leading research into COcapture and its integration with direct electrochemical conversion in the captured state. She is the recipient of multiple awards including an Army Research Office Young Investigator Award, the National Science Foundation CAREER Award, The Electrochemical Society (ECS) Battery Division Early Career Award, an ECS-Toyota Young Investigator Award, the ACS Energy & Fuels Division Glenn Award, the ECS Charles W. Tobias Young Investigator Award, and the Ruth and Joel Spira Award for Distinguished Teaching at MIT. 

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