Research Seminars @ Illinois

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Tailored for undergraduate researchers, this calendar is a curated list of research seminars at the University of Illinois. Explore the diverse world of research and expand your knowledge through engaging sessions designed to inspire and enlighten.

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Hassel and Marianne Ledbetter MatSE Colloquium - "Modeling and measuring the linear viscoelasticity of vitrimer melts"

Event Type
Seminar/Symposium
Sponsor
Materials Science and Engineering Department
Location
100 Materials Science and Engineering Building, 1304 W. Green Street
Date
Feb 10, 2025   4:00 pm  
Speaker
Prof. Ralm Ricarte
Contact
Bailey Peters
E-Mail
bnpeters@illinois.edu
Views
6
Originating Calendar
MatSE Colloquium Calendar

Modeling and measuring the linear viscoelasticity of vitrimer melts

A vitrimer is a polymer network that possesses dynamic covalent cross-links which engage in an associative exchange – i.e., new bonds form before old linkages break. The associative cross-links maintain network connectivity while allowing topology changes, making vitrimers insoluble yet processable at high temperatures. While these paradoxical traits make vitrimers potentially useful for enhancing polymer sustainability, the relationship between their molecular structure and macroscopic viscoelasticity remains an open question. Here, we use a combination of theory and experiment to illuminate structure-viscoelasticity relationships for unentangled vitrimer melts. First, we develop a generalized inhomogeneous Rouse model (IHR) that accounts for interactions between relaxation modes of the regular backbone monomers and associative cross-links. Using the IHR to evaluate the effect of molecular structure and temperature, two distinct relaxation regimes are identified: (I) segmental motions of the backbone at short times and (II) network strand relaxation and cross-link exchange at long times. Next, we experimentally evaluate the viscoelasticity of polybutadiene vitrimers with dioxaborolane cross-links (glass transition temperature Tg < 0 °C) and polystyrene vitrimers with imine cross-links (Tg > 100 °C). The rheological behaviors are compared to the IHR predictions to gauge the impact of molecular structure and temperature on vitrimer relaxation.

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