Hassel and Marianne Ledbetter MatSE Colloquium - “Macromolecule sequence definition for advanced materials design”
- Event Type
- Seminar/Symposium
- Sponsor
- Materials Science and Engineering Department
- Location
- 100 Materials Science and Engineering Building, 1304 W. Green Street, Urbana
- Date
- Oct 24, 2022 4:00 pm
- Speaker
- Christopher Akinleye Alabi, Robert Frederick Smith School of Chemical and Biomolecular Engineering, Cornell University
- Views
- 83
- Originating Calendar
- MatSE Colloquium Calendar
“Macromolecule sequence definition for advanced materials design”
Hierarchical self-assembly of functional materials with predictable properties requires the design and synthesis of programmable building blocks that encode information for self-organization across multiple length scales. Motivated by these opportunities and the need for sequence-control and structural diversity in polymeric materials research, I will present a versatile strategy for the assembly of sustainable cross-linkable sequence-defined macromolecules. This new sequence-defined oligocarbamate (SeDOC) platform overcomes the scalability issue that plagues the iterative assembly of sequence-defined macromolecules and enables the assembly of oligocarbamate macromers at the gram-scale. Data highlighting the effect of sequence on network topology, optical and mechanical properties will be discussed. Furthermore, I will discuss our research efforts toward designing a programmable macromer platform with molecular recognition motifs that can be used in non-aqueous media to encode information for hybridization. I will present data on selective pairs of complementary SeDOCs, characterized using multiple techniques, that can be created at scale and potentially used as ligands in a variety of chemical and materials applications.