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Materials Science and Engineering Colloquium

Event Type
Materials Science and Engineering
100 Materials Science and Engineering Building
Feb 24, 2020   4:00 pm  
Robert Macfarlane, Department of Materials Science and Engineering, MIT

"Systems-level control of structural hierarchy"


Structural hierarchy is a powerful design concept where specific geometric motifs are used to influence material structure across multiple size regimes. These complex levels of organization are typically achieved in the laboratory by manipulating the thermodynamics of chemical bonding between small-scale components to control how they build up into larger length scale patterns. Conversely, complex assemblies in natural systems are commonly achieved through a more holistic approach where not only does structural information contained in molecular building blocks filter upwards to dictate material form at the nano to macroscopic levels, but also that the environment created by the larger length scale features affects the behavior of individual components. Here, we will discuss a new method to synthesize materials in a systems-focused approach that mimics nature’s ability to general complex structural motifs across a wide range of size regimes. This synthesis technique uses nanoscale design handles to deliberately control the multivalent assembly of particle-grafted supramolecular binding moieties, where control over both molecular and nanostructure of material building blocks is then used to manipulate the mesoscale structure of the resulting materials. Assembling materials in this manner therefore expands our ability to program hierarchical ordering at the molecular, nano, and macroscale simultaneously.

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