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CHBE 565 Seminar, Prof. Paul Dauenhauer, University of Minnesota, "Programmable Catalysts for Faster Surface Chemistry: The Catalytic Mechanics of Dynamic Surfaces" (host: Flaherty)

Event Type
Seminar/Symposium
Sponsor
Chemical & Biomolecular Engineering and International Paper Company
Location
116 Roger Adams Laboratory
Date
Sep 2, 2021   2:00 pm  
Contact
Christy Bowser
E-Mail
cbowser@illinois.edu
Views
2

The emergence of competitive renewable energy from sunlight and wind heightens the importance of moving and storing energy from the place of origin to the locations where people live and work.  Chemically capturing energy as compressed hydrogen or energy liquids including hydrocarbons and ammonia remains a leading method of energy storage based on density and fungibility, but the catalytic technology necessary for transformation of electricity into chemicals in small, distributed energy systems is the key challenge for implementation.  In this work[1], we propose to utilize electronically tunable catalytic surfaces (catalytic field effect transistors or CATFETs) to promote the reactions of hydrogen production and hydrogen storage as ammonia.  The general approach of dynamic catalyst operation is described as oscillatory binding energy of adsorbates on active sites as a method to dramatically accelerate the rate of catalytic reaction.  Surface oscillations in sinusoidal and square waveforms of transient binding energy are imposed on catalyst surfaces with varying amplitude and frequency to identify the resonance conditions leading to 10,000x enhancement in overall reaction rate.  The results are presented in the context of catalyst-reaction behavior and with regard to implementation in industrial reactor technologies necessary for moving and storing renewable energy[2].

 

References[1] M.A. Ardagh, O. Abdelrahman, P.J. Dauenhauer, “Principles of Dynamic Heterogeneous Catalysis:  Surface Resonance and Turnover Frequency Response” ACS Catalysis, 2019, 9(8), 6929-6937

[2] M. Shetty, et al. “The Catalytic Mechanics of Dynamic Surfaces:  Stimulating Methods for Promoting Catalytic Resonance,” ACS Catalysis, 2020, DOI:  10.1021/acscatal.0c03336

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